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  • Product Name:   [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
  • Synonyms:   1.3-Bis(dipheny phosphine) propane nickel(II)chloride;DICHLORO[1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE] NICKE;NICL2(DPPP)/ 1,3-BIS(DIPHENY PHOSPHINE) PROPANE NICKEL(II)CHLORIDE;NiCl2(DPPP)NiCl2(DPPP);1,3-Bis-(diphenylphosphino)-propane nickel chloride
  • CAS No.:   15629-92-2
  • Molecular Formula:   C27H26Cl2NiP2
  • Molecular Weight :   542.04
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride



[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Chemical Properties


Melting point  213 °C (dec.)(lit.)


form  crystal


color  red


Water Solubility  insoluble


InChIKey ZBQUMMFUJLOTQC-UHFFFAOYSA-L


CAS DataBase Reference 15629-92-2(CAS DataBase Reference)




Safety Information


Hazard Codes  T,Xn


Risk Statements  49-36/37/38-42/43-40


Safety Statements  53-26-36/37/39-45-24-22


RIDADR  3282


WGK Germany  3


10-21


TSCA  No




[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Usage And Synthesis


Reaction
  1. Nickel catalyst used in the N-heterocycle-directed cross-coupling of fluorinated arenes with organozinc reagents.
  2. Nickel catalyst used in the (E)-selective semihydrogenation of internal alkynes.
  3. Nickel catalyst used in the borylation of halides and pseudohalides.


Chemical Properties red to red-brown powder or crystals


Uses suzuki reaction




[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Preparation Products And Raw materials


Raw materials Etanol-->Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->PETROLEUM ETHER-->Triphenylphosphine-->Litium-->Nickel(II) chloride hexahydrate-->Diphenylphosphine-->1,3-Bis(diphenylphosphino)propane-->1,3-Dibromopropane-->1,3-Dichloropropane


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