Home >> Product >> Photolectric materials >> 2-Bromofluorene
←Return Back
  • Product Name:   2-Bromofluorene
  • Synonyms:   2-bromo-9h-fluorene;4-Bromo-2,2'-methylenebiphenyl
  • CAS No.:   1133-80-8
  • Molecular Formula:   C13H9Br
  • Molecular Weight :   245.11
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of 2-Bromofluorene
2-Bromofluorene Chemical Properties
Melting point  112-114 °C(lit.)
Boiling point  185 °C135 mm Hg(lit.)
density  1.4187 (rough estimate)
refractive index  1.6290 (estimate)
Fp  185°C/135mm
solubility  Soluble in chloroform and ethyl acetate.
form  Slightly Crystalline Powder or Flakes
color  White to slightly yellow
BRN  1946701
InChIKey FXSCJZNMWILAJO-UHFFFAOYSA-N
CAS DataBase Reference 1133-80-8(CAS DataBase Reference)
NIST Chemistry Reference 9H-Fluorene, 2-bromo-(1133-80-8)
Safety Information
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
HazardClass  IRRITANT
2-Bromofluorene Usage And Synthesis
Outline 2-bromofluorene is often used as synthetic intermediate of the OLED material in industry, by the reaction of barbier-type ultrasonic radiation, 2-bromofluorene is also used to study the conversion of aryl bromides to aryl triethoxy silane.
Lab Preparation Methods: propylene carbonate is used as solvent, N-bromosuccinimide (NBS) is used as brominated reagent to carry bromination reaction of fluorine, and this reaction can synthesize 2-bromofluorene and 2,7-dibromofluorene. By the investigation of reaction temperature, NBS amount, the adding methods, the optimal reaction conditions for the synthesis of 2-bromofluorene is confirmed. The optimal reaction conditions are: reaction temperature is 23℃, the molar ratio of NBS with fluorine is 1.1:1, NBS is added by stage addition. First fluorene and propylene carbonate is preheated to 60℃, so fluorine is all dissolved, and then it drops to the reaction temperature, NBS is added by stage addition. 2-bromofluorene and 2,7-dibromofluorene recrystallizes with ethanol and acetic acid respectively, the purity of target product of liquid chromatography can reach more than 99%.
Uses (1) It can be used as pharmaceutical intermediate, it is also important intermediate in the synthesis of optoelectronic material.
(2) By ultrasonic radiation of Barbier-type reaction, 2-bromofluorene is used for the study of aryl bromide (aryl bromides) converts to aryl triethoxysilane (aryltriethoxysilanes). It is also for the preparation of N-carbazole fluorene oligomers end-capped. It can be used as intermediates of OLED materials in industry.
Chemical Properties white to slightly yellow crystalline powder
2-Bromofluorene Preparation Products And Raw materials
Preparation Products 2-Bromo-9,9-dimethylfluorene

  Please leave your message to us :

    ( Your Information is an important part of our business,and we will not share or sell any of it to anyone.)

 
Your Name:
Email:
Product: 2-Bromofluorene
Message:
 

2-Bromofluorene related products :

2-IODO-9H-FLUORENE |9-FLUORENOL |2-Acetylfluorene |2,7-Dibromo-9,9-dimethylfluorene |7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene |9,9-Dimethyl-2-nitro-9H-fluorene |9,9-Dimethyl-9H-fluoren-2-yl-boronic acid |2,7-Di-tert-butylfluorene |2'-broMo-2,7-di-tert-butyl-9,9'-spirobi[fluorene] |9,9'-Spirobi[9H-fluorene] |2,7-Dibromo-9,9-diphenylfluororene |2-Bromo-9,9-diphenylfluorene |9,9-Dimethyl-9H-fluoren-2-ol |2-Bromo-9-phenyl-9H-fluoren-9-ol |2-Bromospiro[9H-fluorene-9,9'-[9H]xanthene] |4-Bromo-spiro[9H-fluorene-9,9'-[9H]xanthene] |Boronic acid, B-9,9'-spirobi[9H-fluoren]-2'-yl- |9,9-Diphenylfluorene |9-Phenyl-9-fluorenol |N-[1,1'-Biphenyl]-2-yl-9,9-dimethyl-9H-fluoren-2-amine |N-([1,1'-biphenyl]-3-yl)-9,9-dimethyl-9H-fluoren-2-amine |N-([1,1':3',1''-terphenyl]-5'-yl)-9,9-dimethyl-9H-fluoren-2-amine |9H-Fluoren-2-amine, 9,9-dimethyl-N-(4-methylphenyl)- |N-[1,1'-biphenyl]-4-yl-N-(4-broMophenyl)-9,9-diMethyl-9H-Fluoren-2-aMine |9,9-Didecyl-2,7-dibromofluorene |9 9-DIDODECYL-2 7-DIBROMOFLUORENE 97 |4 - boric acid - 9, 9 - dimethyl fluorene |4 - boric acid pinacol ester - 9, 9 - dimethyl fluorene |1,3,2-DIOXABOROLANE, 2-(9,9-DIMETHYL-9H-FLUOREN-2-YL)-4,4,5,5-TETRAMETHYL |2,2'-DIBROMO-9,9'-SPIROBIFLUORENE |9,9-Dimethyl-9H-2,7-diiodofluorene |2-Bromo-9,9-di-n-butylfluoren |2-Bromo-9,9-dihexyl fluorene |2-Bromo-9,9-diethylfluorene |4-BroMo-9,9-diphenyl-9H-fluorene |4-BroMo-9,9-diMethyl fluorene |4-bromo-9,9'-Spirobi[9H-fluorene |9,9-Diphenylfluorene-2-Boronic acid pinacol ester |9,9-Dihexyl-9H-fluoren-2-boronic acid |9,9-diphenyl-9H-fluoreN-2-ylboronicacid |

Products

Contact Us

  • Email: info@vosunbio.com
  • Tel:+86-512-66566131,89888618
  • sales extension 8002