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  • Product Name:   (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
  • Synonyms:   JOSIPHOS SL-J002-1;(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE;(R)-(-)-1-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE;(R)-(-)-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE;(R,R)-1-[1-(DI-TERT-BUTYLPHOSPHINO)ETHYL]-2-(DIPHENYLPHOSPHINO)FERROCENE
  • CAS No.:   155830-69-6
  • Molecular Formula:   C32H40FeP2 10*
  • Molecular Weight :   542.45
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of (R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Chemical Properties
alpha  -412° ±15° (c 0.5, CHCl3)
form  Powder
color  Orange
Safety Information
Risk Statements  20/21/22-36/37/38
Safety Statements  24/25
WGK Germany  3
F  10
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Usage And Synthesis
Reaction
  1. Ligand for Palladium-catalyzed amination of aryl halides
  2. Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene
  3. Ligand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with organoboronic acids
  4. Ligand for Copper-catalyzed asymmetric 1,4-hydrosilylations of α,β-unsaturated esters
  5. Ligand for Ruthenium-catalyzed asymmetric hydrogenation of N-sulfonated-α-dehydroamino acids
  6. Ligand for Rhodium-catalyzed asymmetric hydrogenation of enamines
  7. Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates
  8. Ligand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides
  9. Ligand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a C-C bond
Chemical Properties Orange powder
(R)-1-[(1S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLDI-TERT-BUTYLPHOSPHINE Preparation Products And Raw materials
Raw materials Hydrochloric acid-->Ethyl acetate-->Dichloromethane-->Acetic acid glacial-->Potassium carbonate-->Acetic anhydride-->n-Butyllithium-->Lithium aluminium hydride-->Magnesium-->Phosphorus trichloride-->2-Chloro-2-methylpropane-->Chlorodiphenylphosphine-->(R)-(+)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE

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