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  • Product Name:   Bis(triphenylphosphine)nickel(II)chloride
  • Synonyms:   Bis (triphenylphosphine) nickel chloride;NiCl2(PPh3)2;Bis(triphenylphosphine)nickel(II) dichloride 99.99% trace metals basis;Bis(triphenylphosphine)nickel(II) dichloride synthesis grade;Bis(triphenylphosphine)nickel(II) chloride for synthesis
  • CAS No.:   14264-16-5
  • Molecular Formula:   C36H30Cl2NiP2
  • Molecular Weight :   654.17
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Bis(triphenylphosphine)nickel(II)chloride
Bis(triphenylphosphine)nickel(II)chloride Chemical Properties
Melting point  250 °C (dec.)(lit.)
storage temp.  Store below +30°C.
form  Crystals or Powder
color  Dark green to dark gray
Water Solubility  insoluble
Sensitive  Hygroscopic
CAS DataBase Reference 14264-16-5(CAS DataBase Reference)
NIST Chemistry Reference dichlorobis(triphenylphosphine)nickel(14264-16-5)
Safety Information
Hazard Codes  T
Risk Statements  45-43-52/53-34-20/21/22
Safety Statements  53-36/37-45-60-36/37/39-26
RIDADR  3260
WGK Germany  3
RTECS  QR6170000
F  21
TSCA  Yes
HazardClass  6.1(b)
PackingGroup  III
HS Code  29310095
Bis(triphenylphosphine)nickel(II)chloride Usage And Synthesis
Reaction
  1. Catalyst for hydrosilylation of styrene with diphenysilane
  2. Catalyst for carboxylation of various aryl chlorides and other derivatives
  3. Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
  4. Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
  5. Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
Chemical Properties dark green to dark grey crystals or powder
Uses Coordination compund.
Uses suzuki reaction
Purification Methods Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]
Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials
Preparation Products 6,6'-Dimethyl-2,2'-dipyridyl-->3-PHENYLPIPERIDINE
Raw materials Etanol-->Dichloromethane-->Triphenylphosphine-->Nickel(II) chloride hexahydrate

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