4-Bromobenzenesulfonyl chloride Chemical Properties | |
Melting point | 74 °C |
Boiling point | 153 °C15 mm Hg(lit.) |
density | 1.7910 (estimate) |
Fp | 152-154°C/26mm |
storage temp. | Refrigerator, Under Inert Atmosphere |
form | Crystals or Crystalline Powder |
color | White to beige |
Water Solubility | decomposes |
Sensitive | Moisture Sensitive |
Merck | 14,1407 |
BRN | 743518 |
CAS DataBase Reference | 98-58-8(CAS DataBase Reference) |
Safety Information | |
Hazard Codes | C |
Risk Statements | 34 |
Safety Statements | 26-36/37/39-45-27 |
RIDADR | UN 3261 8/PG 2 |
WGK Germany | 3 |
Hazard Note | Irritant |
TSCA | Yes |
HazardClass | 8 |
PackingGroup | II |
HS Code | 29049020 |
4-Bromobenzenesulfonyl chloride Usage And Synthesis | |
Chemical Properties | white to beige crystals or crystalline powder |
Uses | Used for identification of amines, and also in the synthesis and inhibition studies of substituted N-L-histidinylphenylsulfonyl hydrazide. |
Uses | Identification of amines. |
Purification Methods | Wash the sulfonyl chloride with cold water, dry and recrystallise it from pet ether, or from ethyl ether cooled in powdered Dry-Ice after the ether solution had been washed with 10% NaOH until colourless, then dry it with anhydrous Na2SO4. Alternatively dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and recrystallise it. [Huntress & Carten J Am Chem Soc 62 511 1940.] Test for the SO2Cl group by dissolving it in EtOH and boiling with NH4CNS whereby a yellow amorphous precipitate forms on cooling. [Beilstein 11 IV 162.] |
4-Bromobenzenesulfonyl chloride Preparation Products And Raw materials | |
Preparation Products | 4-SULFAMOYLPHENYLBORONIC ACID, PINACOL ESTER-->4-(Aminosulfonyl)phenylboronic acid |
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