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  • Product Name:   4-Bromobenzenesulfonyl chloride
  • Synonyms:   4-bromo-benzenesulfonylchlorid;Benzenesulfonylchloride,4-bromo-;Bromobenzenesulfonylchloride;AKOS BBS-00004603;4-BROMOBENZENESULPHONYL CHLORIDE
  • CAS No.:   98-58-8
  • Molecular Formula:   C6H4BrClO2S
  • Molecular Weight :   255.52
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of 4-Bromobenzenesulfonyl chloride



4-Bromobenzenesulfonyl chloride Chemical Properties


Melting point  74 °C


Boiling point  153 °C15 mm Hg(lit.)


density  1.7910 (estimate)


Fp  152-154°C/26mm


storage temp.  Refrigerator, Under Inert Atmosphere


form  Crystals or Crystalline Powder


color  White to beige


Water Solubility  decomposes


Sensitive  Moisture Sensitive


Merck  14,1407


BRN  743518


CAS DataBase Reference 98-58-8(CAS DataBase Reference)




Safety Information


Hazard Codes  C


Risk Statements  34


Safety Statements  26-36/37/39-45-27


RIDADR  UN 3261 8/PG 2


WGK Germany  3


Hazard Note  Irritant


TSCA  Yes


HazardClass  8


PackingGroup  II


HS Code  29049020




4-Bromobenzenesulfonyl chloride Usage And Synthesis


Chemical Properties white to beige crystals or crystalline powder


Uses Used for identification of amines, and also in the synthesis and inhibition studies of substituted N-L-histidinylphenylsulfonyl hydrazide.


Uses Identification of amines.


Purification Methods Wash the sulfonyl chloride with cold water, dry and recrystallise it from pet ether, or from ethyl ether cooled in powdered Dry-Ice after the ether solution had been washed with 10% NaOH until colourless, then dry it with anhydrous Na2SO4. Alternatively dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and recrystallise it. [Huntress & Carten J Am Chem Soc 62 511 1940.] Test for the SO2Cl group by dissolving it in EtOH and boiling with NH4CNS whereby a yellow amorphous precipitate forms on cooling. [Beilstein 11 IV 162.]




4-Bromobenzenesulfonyl chloride Preparation Products And Raw materials


Preparation Products 4-SULFAMOYLPHENYLBORONIC ACID, PINACOL ESTER-->4-(Aminosulfonyl)phenylboronic acid


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