Home >> Product >> Noble metals >> Tris(dibenzylideneacetone)dipa ...
←Return Back
  • Product Name:   Tris(dibenzylideneacetone)dipalladium
  • Synonyms:   Bis(dibenzylideneacetone)palladium(0)~Pd_2(dba)_3;Tris(dibenzylidenaceTone) dipalladium (O);Tris(dibezylideneacetone)dipalladium;Palladium, tris.mu.-(1,2-.eta.:4,5-.eta.)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-onedi-;Tris(dibenzylidenaceton)dipalladium
  • CAS No.:   60748-47-2；51364-51-3
  • Molecular Formula:   C51H42O3Pd2
  • Molecular Weight :   915.71738
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Tris(dibenzylideneacetone)dipalladium
Tris(dibenzylideneacetone)dipalladium Chemical Properties
Melting point  152-155°C
storage temp.  2-8°C
solubility  Soluble in chlorinated solvents, benzene and THF.
form  Fine Crystalline Powder
color  Purple to black
Water Solubility  insoluble
Sensitive  Air & Moisture Sensitive
CAS DataBase Reference 51364-51-3(CAS DataBase Reference)
Safety Information
Hazard Codes  Xn
Risk Statements  20/22-36-40
Safety Statements  24/25-36/37
Tris(dibenzylideneacetone)dipalladium Usage And Synthesis
Description Tris(dibenzylideneacetone) dipalladium (Tris DBA) is used as catalyst for a wide variety of Pd catalyzed reactions including Suzuki coupling, Heck coupling, Negishi coupling, Carroll reaarangement, Trost asymmetric allylic alkylation, Buchwald-Hartwig amination of acryl halides, fluorination of allylic chlorides, arylation of ketones, carbonylation of 1,1-dichloro-1-alkenes, ß-arylation of carboxylic esters, and conversion of aryl and vinyl triflates to aryl and vinyl halides. It is also involved in the synthesis of azepane. Tris DBA is also a novel inhibitor of N-myristoyltransferase-1 with significant antitumor activity.
Reactions 1. Catalyst precursor for conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics.
2. Catalyst for the synthesis of epoxides.
3. Catalytic asymmetric allylic and homoallylic diamination of terminal olefins.
4. Site-selective benzylic sp3 palladium-catalyzed direct arylation.
5. Palladium-catalyzed one-pot synthesis of tricyclic indolines.
6. Active catalyst for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles.
7. Catalyst in combination with BINAP for the asymmetric Heck Arylation of olefins.
8. Precursor for palladium-catalyzed carbon-nitrigen bond formation.
9. Catalyst for α-arylation of ketones,
10. Cross-coupling of aryl halides with aryl boronic acids.
References
  1. https://en.wikipedia.org/wiki/Tris(dibenzylideneacetone)dipalladium(0)
  2. http://www.sigmaaldrich.com
  3. https://www.alfa.com
  4. https://pubchem.ncbi.nlm.nih.gov
  5. S. S. Bhandarkar, J. Bromberg, C. Carrillo, P. Selvakumar, R. K. Sharma, B. N. Perry, B. Govindarajan, L. Fried, A. Sohn, K. Reddy and J. L. Arbiser, Tris (Dibenzylideneacetone) Dipalladium, a N-Myristoyltransferase-1 Inhibitor, Is Effective against Melanoma Growth In vitro and In vivo, Clinical Cancer Research, 2008, vol. 18, 5743-5748
Chemical Properties dark purple solid
Uses suzuki reaction
Uses A cycloaddition catalyst.
Tris(dibenzylideneacetone)dipalladium Preparation Products And Raw materials
Preparation Products 3-MORPHOLINOPHENYLBORONIC ACID PINACOL ESTER-->4-PYRIDIN-2-YLISOXAZOL-5-AMINE-->3-Morpholinobenzaldehyde
Raw materials Sodium acetate-->Benzaldehyde-->Palladium chloride

  Please leave your message to us :

    ( Your Information is an important part of our business,and we will not share or sell any of it to anyone.)

 
Your Name:
Email:
Product: Tris(dibenzylideneacetone)dipalladium
Message:
 

Tris(dibenzylideneacetone)dipalladium related products :

Bis(triphenylphosphine)palladium(II) chloride |Dichloro(1,5-cyclooctadiene)palladium(II) |1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex |Bis(benzonitrile)palladium chloride |[1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) |Tris(dibenzylideneacetone)dipalladium-chloroform adduct |Palladium pivalate 97% |Bis(triphenylphosphinepalladium) acetate |CHLORO(DI-2-NORBORNYLPHOSPHINO)(2-DIMETHYLAMINOMETHYLFERROCEN-1-YL)PALLADIUM(II) |DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) |RUTHENIUM CARBONYL |TETRAPROPYLAMMONIUM PERRUTHENATE |DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) |Dichloro(cycloocta-1,5-diene)ruthenium(II) |Diiodo(p-cymene)ruthenium(II) dimer |Ruthenium acetylacetonate |Rhodium chloride trihydrate |Rhodium acetate |Chloro(1,5-cyclooctadiene)rhodium(I) dimer |Rhodium(III) nitrate dihydrate |Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate |Chloroplatinic acid |Ammonium chloroplatinate |Tetrakis(triphenylphosphine)platinum |Tetraammineplatinum(II) chloride hydrate |Tetraammineplatinum dinitrate |Diamminedinitritoplatinum(II) |Potassium chloroplatinate |dipotassium tetrachloroplatinate |Platinum nitrate |Platinum dioxide |Platinum dichloride |Dihydrogen hexahydroxyplatinate |Dinitrosulfatoplatinum |Platinum bis(acetylacetonate) |Cisplatin |Dichloro(1,5-cyclooctadiene)platinum(II) |Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane |Palladium |Palladium chloride |

Products

Contact Us

  • Email: info@vosunbio.com
  • Tel:+86-512-66566131,89888618
  • sales extension 8002