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- Product Name: TETRAPROPYLAMMONIUM PERRUTHENATE
- Synonyms: TETRA-N-PROPYLAMMONIUM PERRUTHENATE;TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII);TPAP;Tetrapropylammoniumperruthenate,min.97%TPAP;1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-)
- CAS No.: 114615-82-6
- Molecular Formula: C12H28NO4Ru
- Molecular Weight : 351.43
- Specification : 98%
- Place of Origin: China
- Appearance :
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Description of TETRAPROPYLAMMONIUM PERRUTHENATE
| TETRAPROPYLAMMONIUM PERRUTHENATE Chemical Properties | |
| Melting point | ~160 °C (dec.)(lit.) |
| storage temp. | 2-8°C |
| form | crystal |
| color | green |
| Water Solubility | Insoluble in water. |
| Sensitive | Hygroscopic |
| Stability: | store cold |
| Safety Information | |
| Hazard Codes | O,Xi |
| Risk Statements | 5-8-36/37/38 |
| Safety Statements | 17-26-36 |
| RIDADR | UN 1479 5.1/PG 2 |
| WGK Germany | 3 |
| F | 3-10 |
| HazardClass | 5.1 |
| PackingGroup | III |
| TETRAPROPYLAMMONIUM PERRUTHENATE Usage And Synthesis | |
| Uses | A mild oxidant for the selective transformation of primary alcohols to aldehydes and secondary alcohols to ketones. |
| Chemical Properties | dark green solid |
| Definition | ChEBI: A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion. |
| Purification Methods | It is a strong oxidant and may explode on heating. It can be washed with aqueous n-propanol, then H2O and dried over KOH in a vacuum. It is stable at room temperature but best stored in a refrigerator. It is soluble in CH2Cl2 and MeCN. [Dengel et al. Transition Met Chem 10 98 1985, Griffith et al. J Chem Soc, Chem Commun 1625 1987.] § Polymer supported reagent is available commercially. |
| TETRAPROPYLAMMONIUM PERRUTHENATE Preparation Products And Raw materials | |
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