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  • Product Name:   Bis(benzonitrile)palladium chloride
  • Synonyms:   TRANS-BIS-(BENZONITRILE)PALLADIUM(II) CHLORIDE;Bis(benzonitrile)palladium(II) chloride, 99+%;Dichlorobis(benzonitrile)palladium(II),99%;Palladium, bis(benzonitrile)dichloro-;Palladium(II)chloro-bis(benzonitrile)
  • CAS No.:   14220-64-5
  • Molecular Formula:   C14H10Cl2N2Pd
  • Molecular Weight :   383.57
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Bis(benzonitrile)palladium chloride



Bis(benzonitrile)palladium chloride Chemical Properties


Melting point  131 °C(lit.)


storage temp.  Store below +30°C.


solubility  Soluble in acetone, chloroform


form  Crystalline Powder


color  Orange to brown


Water Solubility  insoluble


CAS DataBase Reference 14220-64-5(CAS DataBase Reference)




Safety Information


Hazard Codes  Xn


Risk Statements  20/21-23/24/25


Safety Statements  22-24/25-23-45-36/37-27-20-9-4


RIDADR  UN3439


WGK Germany  3


9


TSCA  No


HazardClass  6.1


PackingGroup  III


HS Code  28439090




Bis(benzonitrile)palladium chloride Usage And Synthesis


Reaction
  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.



Chemical Properties yellow powder


Uses suzuki reaction


Uses Catalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.




Bis(benzonitrile)palladium chloride Preparation Products And Raw materials


Preparation Products Chlorodimethylphenylsilane


Raw materials Toluene-->Palladium chloride-->Benzonitrile


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