2-Chloro-1-methylpyridinium iodide Chemical Properties | |
Melting point | 200 °C (dec.)(lit.) |
density | 1.7949 (estimate) |
storage temp. | Store at 0-5°C |
form | Crystalline Powder and/or Chunks |
color | Yellow |
Water Solubility | soluble |
Sensitive | Moisture & Light Sensitive |
Merck | 14,6301 |
BRN | 3572320 |
CAS DataBase Reference | 14338-32-0(CAS DataBase Reference) |
EPA Substance Registry System | Pyridinium, 2-chloro-1-methyl-, iodide(14338-32-0) |
Safety Information | |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-24/25-36 |
RIDADR | 1759 |
WGK Germany | 3 |
F | 8-21 |
HazardClass | 8 |
PackingGroup | III |
HS Code | 29333999 |
2-Chloro-1-methylpyridinium iodide Usage And Synthesis | |
Chemical Properties | yellow crystalline solid |
Uses | Condensation reagent for the synthesis of esters and ketenes, and for the kinetic resolution of carboxylic acids and alcohols. |
Purification Methods | Purify it by dissolving in EtOH and adding dry Et2O. The solid is washed with Me2CO and dried at 20o/0.35mm. Store it in the dark. Attempted recrystallisation from Me2CO/EtOH/pet ether (b 40-60o) causes some exchange of the Cl substituent by I. The picrate has m 106-107o, and the perchlorate has m 212-213o. [Jones et al. J Am Chem Soc 111 1157 1989, UV and solvolysis: Barlin & Benbow J Chem Soc, Perkin Trans 2 790 1974, Beilstein 20/5 V 405.] |
2-Chloro-1-methylpyridinium iodide Preparation Products And Raw materials | |
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