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  • Product Name:   Bis(pinacolato)diboron
  • Synonyms:   BIS(2,2,3,3-TETRAMETHYL-2,3-BUTANEDIONATO)DIBORON;BIS(PINACOLATO)DIBORANE;DIBORON PINACOL ESTER;4,4,4',4',5,5,5',5'-OCTAMETHYL-2,2'-BL-1,3,2-DIOXABOROLANE;4,4,4',4',5,5,5',5'-OCTAMETHYL-2,2'-BIS(1,3,2-DIOXABOROLANE)
  • CAS No.:   73183-34-3
  • Molecular Formula:   C12H24B2O4
  • Molecular Weight :   253.93856
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Bis(pinacolato)diboron



Bis(pinacolato)diboron Chemical Properties


Melting point  137-140 °C(lit.)


density  0.98


storage temp.  0-6°C


form  Powder or Platelets


color  White


Water Solubility  Soluble in tetrahydrofuran, dichloromethane, toluene, hexane and heptane. Insoluble in water.


Sensitive  moisture sensitive


Merck  14,1300


BRN  7703552


CAS DataBase Reference 73183-34-3(CAS DataBase Reference)




Safety Information


Hazard Codes  Xi,Xn


Risk Statements  36/37/38-20/21/22


Safety Statements  26-37/39-36-24/25


WGK Germany  3


Hazard Note  Irritant


HazardClass  IRRITANT, IRRITANT-HARMFUL, KEEP COLD




Bis(pinacolato)diboron Usage And Synthesis


Reaction
  1. Reagent used for the synthesis of aryl, alkenyl, allyl and alkylboronic esters.
  2. Reagent used for the borylation of an α,β-unsaturated ketones.
  3. Reagent used for the synthesis of precursors for conducting polymers.
  4. Reagent used for the synthesis of in vivo fluorescent probes.
  5. Reagent used for the diborylation of alkynes. 




Chemical Properties white crystal powder


Uses suzuki reaction


Uses Bis(pinacolato)diboron is used as a condensation agent in the preparation poly(arylene)s. Bis(pinacolato)diboron is an organoboranate with potential use as matrix metallo-proteinase (MMP-2) inhibitor.


Uses As a boron source in Pt-mediated diborations, coupling reactions; in Rh-or Ir-mediated borylations of alkanes and arenes, and in carbenoid chemistry.




Bis(pinacolato)diboron Preparation Products And Raw materials


Preparation Products TERT-BUTYL 5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)ISOINDOLINE-2-CARBOXYLATE-->4-Nitrophenylboronic acid-->4-AMINO-3-METHOXYPHENYLBORONIC ACID, PINACOL ESTER


Raw materials Ethyl acetate-->Sodium-->PETROLEUM ETHER-->Toluene-->Cyclohexane-->Pentane-->Tetrahydro pyrrole-->Boron tribromide-->Pinacol


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