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  • Product Name:   (R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
  • Synonyms:   ALPHA,ALPHA-DIPHENYL-D-PROLINOL METHYLBORONIC ACID CYCL-AMIDE-ESTER;(R)-(+)-2-METHYL-CBS-OXAZABOROLIDINE;(R)-2-METHYL-CBS-OXAZABOROLIDINE;(R)-2-METHYL-CBS-OXAZABOROLIDINE MONOHYDRATE;(R)-1-METHYL,3,3-DIPHENYL-TETRAHYDRO-PYRROLO(1,2-C)(1,3,2)OXAZABOROLE
  • CAS No.:   112022-83-0
  • Molecular Formula:   C18H20BNO
  • Molecular Weight :   277.17
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of (R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Chemical Properties
Melting point  85-95 °C(lit.)
Boiling point  111 °C
density  0.95 g/mL at 25 °C
refractive index  68 ° (C=1, MeOH)
Fp  40 °F
storage temp.  2-8°C
form  Liquid
color  Colorless to amber
Water Solubility  Not miscible or difficult to mix in water.
Sensitive  Air & Moisture Sensitive
BRN  9059874
InChIKey VMKAFJQFKBASMU-QGZVFWFLSA-N
CAS DataBase Reference 112022-83-0(CAS DataBase Reference)
Safety Information
Hazard Codes  F,Xn,Xi
Risk Statements  11-38-48/20-63-65-67-36/37-19-40
Safety Statements  36/37-62-33-29-16-2-26
RIDADR  UN 1294 3/PG 2
WGK Germany  3
F  10
HazardClass  3
PackingGroup  II
HS Code  29319090
(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Usage And Synthesis
Reactions
  1. Convenient catalyst for the enantioselective borane reduction of ketones at ambient temperatures.
  2. Asymmetric synthesis of α-chiral hydroxyalkylphosphines via a catalytic, enantioselective reduction of acylphosphines.
  3. Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: Stereospecific formation of diarylalkanes and triarylmethanes.
  4. Enantioselective reduction of prochiral ketones with NaBH4/Me2SO4/(S)-Me-CBS. 
Chemical Properties white to light yellow crystal powde
Uses suzuki reaction
(R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Preparation Products And Raw materials
Preparation Products 4H-AMINO-6-BROMO-2,3-DIHYDROTHIOCHROMEN-1,1-DIOXIDE-->4-Hydroxy-6-bromo-2,3-dihydrothiochromen-1,1-dioxide

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