2,4-Dimethyl aniline Chemical Properties | |
Melting point | 16 °C |
Boiling point | 218 °C(lit.) |
density | 0.98 g/mL at 25 °C(lit.) |
vapor density | 4.2 (vs air) |
vapor pressure | 0.16 mm Hg ( 25 °C) |
refractive index | n |
Fp | 195 °F |
storage temp. | room temp |
solubility | 5g/l |
form | Liquid |
color | Clear yellow to red-brown |
PH | 7 (22g/l, H2O, 20℃) |
explosive limit | 1.1-7.0%(V) |
Water Solubility | 5 g/L (20 ºC) |
Merck | 14,10084 |
BRN | 636243 |
Stability: | Stable. Combustible. Incompatible with strong oxidizing agents, acids, acid anhydrides, acid chlorides, chloroformates, halogens. |
CAS DataBase Reference | 95-68-1(CAS DataBase Reference) |
NIST Chemistry Reference | Benzenamine, 2,4-dimethyl-(95-68-1) |
EPA Substance Registry System | Benzenamine, 2,4-dimethyl-(95-68-1) |
Safety Information | |
Hazard Codes | T,N |
Risk Statements | 23/24/25-33-51/53 |
Safety Statements | 28-36/37-45-61-28A |
RIDADR | UN 1711 6.1/PG 2 |
WGK Germany | 2 |
RTECS | ZE8925000 |
F | 8 |
TSCA | Yes |
HazardClass | 6.1 |
PackingGroup | II |
HS Code | 29214910 |
Hazardous Substances Data | 95-68-1(Hazardous Substances Data) |
2,4-Dimethyl aniline Usage And Synthesis | |
Chemical Properties | colourless to yellow or dark brown liquid |
Definition | ChEBI: A primary arylamine that is aniline in which the hydrogens at the 2- and 4-positions are replaced by methyl groups. A clear to yellow liquid, it is used in production of certain dyes, pesticides and other chemicals. |
General Description | Dark brown liquid. |
Air & Water Reactions | 2,4-Dimethyl aniline may be sensitive to prolonged exposure to air. Slightly soluble in water. |
Reactivity Profile | 2,4-Dimethyl aniline ignites on contact with fuming nitric acid . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. |
Fire Hazard | 2,4-Dimethyl aniline is combustible. |
Purification Methods | Convert uns-xylidine to a derivative (see below) which, after recrystallisation, is decomposed with alkali to give the free base. Dry it over KOH and fractionally distil. The acetyl derivative has m 130o, the benzoyl derivative has m 192o, and the picrate has m 209o. [Beilstein 12 H 1111, 12 IV 2545.] |
2,4-Dimethyl aniline Preparation Products And Raw materials | |
Raw materials | m-Xylene-->4-Nitro-1,3-dimethylbenzene-->2,6-Dimethyl-1-nitrobenzene |
Preparation Products | 2,6-Dimethylaniline-->Amitraz-->AMITRAZ METABOLITE HYDROCHLORIDE-->SOLVENT YELLOW 85-->Solvent Yellow 18 |
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