Home >> Product >> Noble metals >> Palladium (II) Acetate
←Return Back
  • Product Name:   Palladium (II) Acetate
  • Synonyms:   ACETIC ACID PALLADIUM(II) SALT;PALLADIUM ACETATE;PALLADIUM(+2)ACETATE;PALLADIUM DIACETATE;PALLADIUM(II) ACETATE
  • CAS No.:   3375-31-3
  • Molecular Formula:   C4H6O4Pd
  • Molecular Weight :   224.51
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Palladium (II) Acetate
Palladium (II) Acetate Chemical Properties
Melting point  205 °C
storage temp.  Store at R.T.
solubility  Soluble as monomer in glacial acetic acid or as trimer in benzene.
form  Various Forms In Red-(Powder/Flake/Crystalline/Beads)
color  Red-brown
PH 2-3 (H2O, 20℃)(aqueous suspension)
Water Solubility  insoluble
Sensitive  Hygroscopic
λmax 400nm(EtOH)(lit.)
Merck  14,6991
InChIKey PCUVQHHZCJMCHO-UHFFFAOYSA-M
CAS DataBase Reference 3375-31-3(CAS DataBase Reference)
EPA Substance Registry System Acetic acid, palladium(2+) salt(3375-31-3)
Safety Information
Hazard Codes  Xi,Xn,C
Risk Statements  41-36/37/38-40-35
Safety Statements  26-39-36/37/39-45-36
RIDADR  3261
WGK Germany  2
RTECS  AJ1900000
F  10-23
TSCA  Yes
HS Code  28439090
Palladium (II) Acetate Usage And Synthesis
Reactions
  1. Efficient catalyst for the arylation of olefins (Heck reaction).
  2. Catalyst for cross-coupling reactions.
  3. Catalyst for C-H activation.
  4. Precatalyst for enantioselective decarboxylative protonation of allyl β-ketoesters. 
Chemical Properties brown needles
Uses suzuki reaction
Uses Palladium (II) Acetate Trimer is used in Suzuki-Miyaura cross-coupling reactions. It also serves to catalyze the chemoselective reduction of nitroarenes.
Uses A catalyst for intramolecular coupling.
Purification Methods It recrystallises from CHCl3 as purple crystals. It can be washed with AcOH and H2O and dried in air. Large crystals are obtained by dissolving it in *C6H6, adding half its volume of AcOH and allowing it to evaporate slowly at room temperature. It forms green adducts with nitrogen donors, it dissolves in KI solution to form solid PdI2 and a red solution of PdI42-, but is insoluble in aqueous saturated NaCl, and NaOAc. It dissolves in HCl to form PdCl42-. It is soluble in CHCl3, CH2Cl2, Me2CO, MeCN, Et2O, but it is insoluble in H2O, and decomposes when warmed in alcohols in which it is also insoluble. [Morehouse et al. Chem Ind (London) 544 1964, Stephenson et al. J Chem Soc 3632 1965, Skapski & Smart J Chem Soc (D) 658 1970, Heck Acc Chem Res 12 146 1979.]
Palladium (II) Acetate Preparation Products And Raw materials
Preparation Products (S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE-->(R)-7,7'-BIS(DIPHENYLPHOSPHINO)-1,1'-SPIROBIINDANE-->Bergapten-->(R)-(+)-7,7'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE-->(R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE-->(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%-->4-(2-KETO-1-BENZIMIDAZOLINYL)PIPERIDINE-->Diphenylacetylene-->C-(3,4-DIHYDRO-2H-BENZO[1,4]OXAZIN-3-YL)-METHYLAMINE-->Ethyl (R)-2-hydroxy-4-phenylbutyrate-->3-AMINOBIPHENYL-->2,3-DIHYDRO-1H-INDOLE-5-CARBOXYLIC ACID-->5-CYANO-2,3-DIHYDRO-1H-INDOLE-->INDOLINE-6-CARBOXYLIC ACID-->ethyl indoline-6-carboxylate-->3-PHENYLBENZYLAMINE-->1-(4-Pyridyl)piperazine-->4,6-Diamino-2-pyrimidinol-->2-MORPHOLINO-5-(TRIFLUOROMETHYL)BENZALDEHYDE-->ethyl 1H-indole-6-carboxylate-->4-AMINOBIPHENYL-->N,N'-Bis- (1-naphthalenyl)-N,N'-bis-phenyl-(1,1'-biphenyl)-4,4'-diamine-->1-ACETYL-5-AMINO-2,3-DIHYDRO-(1H)-INDOLE-->5-Phenylthiophene-2-carboxylic acid-->5-PHENYL-2-THIOPHENECARBALDEHYDE-->(E)-METHYL 3-(4-BROMOPHENYL)ACRYLATE-->4-Aminophenylboronic acid pinacol ester-->5-Methylindole-->3-Phenyl-1H-pyrazole-->Allyl acetate
Raw materials Acetic acid glacial-->Hydrazine hydrate-->Palladium chloride-->Sodium formate

  Please leave your message to us :

    ( Your Information is an important part of our business,and we will not share or sell any of it to anyone.)

 
Your Name:
Email:
Product: Palladium (II) Acetate
Message:
 

Palladium (II) Acetate related products :

Tetrakis(triphenylphosphine)palladium |Bis(2,4-pentanedionato-O,O')palladium(II) |Bis(acetonitrile)dichloropalladium(II) |Bis(dibenzylideneacetone)palladium |[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) |dichlorobis(di-tert-butylphenylphosphine)palladium(II) |1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, |DICHLOROBIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(II) |BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) |Rhodium |Rhodium(III) nitrate |Rhodium (III) chloride trihydrate |Rhodium triiodide |Rhodium(III) sulfate |Rhodium(II) octanoate dimer |Chlorotris(triphenylphosphine)rhodium(I) |Rhodium(II) acetate dimer |Carbonyltris(triphenylphosphine)rhodium(I) hydride |Dicarbonylacetylacetonato rhodium(I) |Rhodium (triphenylphosphine)carbonylacetylacetonate |Rhodium carbonyl chloride |Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] |BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE |(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE |Iridium |Iridium(III) chloride hydrate |Hexachloroiridic acid hexahydrate |Dipotassium hexachloroiridate |Ammonium hexachloroiridate(IV) |Chloro(1,5-cyclooctadiene)iridium(I) dimer |(Pentamethylcyclopentadienyl)iridium(III) chloride dimer |Iridium(III) acetylacetonate |1,2,3-Triaqua-1,2:1,2:1,3:1,3:2,3:2,3-hexa-m-acetato(O,O')-m3-oxo-triangulo-triiridium acetate |Ruthenium |Ruthenium(III) chloride |Ruthenium trichloride |Ruthenium(IV) oxide hydrate |Ruthenium dioxide |hexakis[mu-(acetato-O:O')]-mu3-oxo-triangulo-triruthenium acetate |Ruthenium nitrosyl nitrate |

Products

Contact Us

  • Email: info@vosunbio.com
  • Tel:+86-512-66566131,89888618
  • sales extension 8002