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  • Product Name:   Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
  • Synonyms:   Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium;Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE;DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER
  • CAS No.:   12354-85-7
  • Molecular Formula:   C20H30Cl4Rh2 10*
  • Molecular Weight :   618.08
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]



Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties


Melting point  >300°C


form  crystal


color  red


Water Solubility  Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether


NIST Chemistry Reference Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)




Safety Information


Hazard Codes  Xn


Risk Statements  20/21/22-36/37/38-R36/37/38-R20/21/22


Safety Statements  26-36-S36-S26-24/25


WGK Germany  3




Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Usage And Synthesis


Reaction
  1. Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
  2. Rhodium- catalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
  3. Catalyst used in the asymmetric transfer hydrogenation of imines in water.
  4. Facile rhodium-catalyzed synthesis of fluorinated pyridines.
  5. Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.



Chemical Properties burgundy solid


Uses Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A




Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials


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