Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties | |
Melting point | >300°C |
form | crystal |
color | red |
Water Solubility | Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether |
NIST Chemistry Reference | Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7) |
Safety Information | |
Hazard Codes | Xn |
Risk Statements | 20/21/22-36/37/38-R36/37/38-R20/21/22 |
Safety Statements | 26-36-S36-S26-24/25 |
WGK Germany | 3 |
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Usage And Synthesis | |
Reaction |
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Chemical Properties | burgundy solid |
Uses | Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A |
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials | |
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