3,4-METHYLENEDIOXYPHENYLBORONIC ACID Chemical Properties | |
Melting point | 224-229 °C(lit.) |
storage temp. | 0-6°C |
form | Powder |
color | White to off-white |
BRN | 5523347 |
CAS DataBase Reference | 94839-07-3(CAS DataBase Reference) |
Safety Information | |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 37/39-26 |
WGK Germany | 3 |
Hazard Note | Irritant |
HazardClass | IRRITANT |
3,4-METHYLENEDIOXYPHENYLBORONIC ACID Usage And Synthesis | |
Chemical Properties | White powder |
Uses | Reactant involved in:• ;Petasis reaction between glyoxylic acid, α-amino phosphonates, and organylboronic acids1• ;Mannich-type multicomponent assembly and 1,3-dipolar cycloaddition for synthesis of tetrahydroisoquinoline fused isoxazolidine scafford2• ;Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides3,4• ;Oxidative Heck reaction for synthesis of functionalized cinnamaldehyde derivatives5• ;Intramolecular Alder-ene and Pictet-Spengler reactions for synthesis of crinine6 |
Uses | suzuki reaction |
3,4-METHYLENEDIOXYPHENYLBORONIC ACID Preparation Products And Raw materials | |
Raw materials | Tetrahydrofuran-->Magnesium-->Trimethyl borate-->4-Bromo-1,2-(methylenedioxy)benzene |
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