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  • Product Name:   (1S,2R)-(-)-cis-1-Amino-2-indanol
  • Synonyms:   (1S,2R)-(-)-CIS-1-AMINO-2-HYDROXYINDANE;(1S,2R)-CIS-1-AMINO-2-INDANOL;(1S,2R)-(-)-CIS-1-AMINOINDAN-2-OL;(1S,2R)-(+)-CIS-1-AMINOINDAN-2-OL;(1S,2R)-1-AMINO-2,3-DIHYDRO-1H-INDEN-2-OL
  • CAS No.:   126456-43-7
  • Molecular Formula:   C9H11NO
  • Molecular Weight :   149.19
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of (1S,2R)-(-)-cis-1-Amino-2-indanol



(1S,2R)-(-)-cis-1-Amino-2-indanol Chemical Properties


Melting point  118-121 °C(lit.)


alpha  -62 º (c=0.5, CHCl3)


Boiling point  270.27°C (rough estimate)


density  1.0753 (rough estimate)


refractive index  1.5760 (estimate)


RTECS  NK7525500


form  Powder


color  White to light beige


Water Solubility  slightly soluble


Sensitive  Air Sensitive


CAS DataBase Reference 126456-43-7(CAS DataBase Reference)




Safety Information


Hazard Codes  Xi,Xn


Risk Statements  36/37/38-20/21/22


Safety Statements  26-36-36/37/39


RIDADR  3259


WGK Germany  3


10-23


HazardClass  8




(1S,2R)-(-)-cis-1-Amino-2-indanol Usage And Synthesis


Reaction
  1. Ligand component used in the chromium-catalyzed highly selective asymmetric ene reactions between aryl aldehydes and alkoxy- and silyloxyalkenes.
  2. Ligand component for the chromium-catalyzed highly enantioselective o inverse-demand hetero-Diels-Alder reactions of α,β-unsaturated aldehydes.
  3. Ligand component for the magnesium-catalyzed conjugate addition reaction of 1,3-dicarbonyl compounds to nitroalkenes.
  4. Component for stereoselective asymmetric 6π-azaelectrocyclization through the reaction between the (E)-3-
  5. carbonyl-2,4,6-trienal compounds and the (-)-7-alkyl-cis-1-amino-2-indanol derivatives.
  6. Ligand component for palladium-catalzyed asymmetric azaelectrocyclization for the preparation of 2,4-
  7. disubstituted chiral 1,2,5,6-tetrahydropyridines.
  8. Component for organocatalytic conjugate addition of formaldehyde N,N-dialkylhydrazones to β,γ -Unsaturated α-keto esters.
  9. N-Sulfinyl urea organocatalyst component for enantioselective aza-henry reaction.
  10. Component for organocatalytic enantioselective additions of indoles to nitroalkenes.





Chemical Properties white to light yellow crystal powder




(1S,2R)-(-)-cis-1-Amino-2-indanol Preparation Products And Raw materials


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