1,1'-BINAPHTHYL Chemical Properties | |
Melting point | 143-146 °C |
Boiling point | 360 °C |
density | 1,3 g/cm3 |
refractive index | 1.6292 (estimate) |
form | Powder |
color | Brown |
CAS DataBase Reference | 604-53-5(CAS DataBase Reference) |
Safety Information | |
Safety Statements | 24/25 |
TSCA | Yes |
1,1'-BINAPHTHYL Usage And Synthesis | |
Chemical Properties | Brown powder |
Purification Methods | Purify 1,1’-binaphthyl through a silica gel column with Me2CO/*C6H6 [or Al2O3 with 10% *C6H6/pet ether (b 30-60o)] and recrystallise it from EtOH, pentane, or slow evaporation of *C6H6, Me2CO or Et2O solutions. Half life ~10hours at 25o in various solvents. [Wilson & Pincock J Am Chem Soc 97 1474 1975, Akimoto & Yamada Tetrahedron 27 5999 1971, Beilstein 5 I 358, 5 II 642, 5 III 2465, 5 IV 2634.] |
1,1'-BINAPHTHYL Preparation Products And Raw materials | |
Preparation Products | the BINAP-Rh^<+^> complex |
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