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  • Product Name:   (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
  • Synonyms:   MANDYPHOS SL-M003-1;(R,R)-1,1'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE;(S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-DI[BIS(3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINO]FERROCENE;(aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis{bis[3,5-bis(trifl;(S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-trifluoromethylphenyl)phosphino)ferrocene
  • CAS No.:   494227-36-0
  • Molecular Formula:   C60H42F24FeN2P2 10*
  • Molecular Weight :   1364.74
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Chemical Properties
alpha  -250.2° (c 1.0, CHCl3)
form  solid
color  orange-red
Stability: store cold
Safety Information
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Usage And Synthesis
Reaction
  1. Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates.
  2. Ligand for Rh-catalyzed hydrogenation of α- and β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3- diketones.
  3. Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives.
  4. Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones.
  5. Ligand for Cu-catalyzed enantioselective hydroboration of α- and β-unsaturated esters and nitriles.
Chemical Properties Orange powder
(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Preparation Products And Raw materials

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Product: (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE
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(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE related products :

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