1,3-Dichlorobenzene Chemical Properties | |
Melting point | -24 °C |
Boiling point | 172-173 °C(lit.) |
density | 1.288 g/mL at 25 °C(lit.) |
vapor pressure | 5 mm Hg ( 38.8 °C) |
refractive index | n |
Fp | 146 °F |
storage temp. | 0-6°C |
solubility | Difficult to mix. |
form | Liquid |
color | Clear colorless to slightly yellow |
Water Solubility | 0.0123 g/100 mL (25 ºC) |
FreezingPoint | -24℃ |
Merck | 14,3055 |
BRN | 956618 |
Stability: | Stability Combustible. Incompatible with strong oxidizing agents, aluminium, aluminium alloys. Moisture-sensitive. |
InChIKey | ZPQOPVIELGIULI-UHFFFAOYSA-N |
CAS DataBase Reference | 541-73-1(CAS DataBase Reference) |
NIST Chemistry Reference | Benzene, 1,3-dichloro-(541-73-1) |
Safety Information | |
Hazard Codes | Xn,N,T,F |
Risk Statements | 22-51/53-39/23/24/25-23/24/25-11 |
Safety Statements | 61-45-36/37-16-7 |
RIDADR | UN 3082 9/PG 3 |
WGK Germany | 2 |
RTECS | CZ4499000 |
TSCA | Yes |
HazardClass | 6.1(b) |
PackingGroup | III |
HS Code | 29036990 |
Hazardous Substances Data | 541-73-1(Hazardous Substances Data) |
1,3-Dichlorobenzene Usage And Synthesis | |
Chemical Properties | colourless liquid |
Definition | ChEBI: A dichlorobenzene carrying chloro substituents at positions 1 and 3. |
General Description | Colorless liquid. Sinks in water. |
Air & Water Reactions | 1,3-Dichlorobenzene is sensitive to moisture. Insoluble in water. |
Reactivity Profile | 1,3-Dichlorobenzene is incompatible with oxidizing agents and aluminum and its alloys. Above the flash point, explosive vapor-air mixtures may be formed. |
Health Hazard | INHALATION: Causes headache, drousiness, unsteadiness. Irritating to mucous membranes. EYES: Severe irritation. SKIN: Severe irritation. INGESTION: Irritation of gastric mucosa, nausea, vomiting, diarrhea, abdominal cramps and cyanosis. |
Fire Hazard | Special Hazards of Combustion Products: Irritating vapors including hydrogen chloride are produced. |
Purification Methods | Wash it with aqueous 10% NaOH, then with water until neutral, dry and distil it. Conductivity material (ca 10-10 mhos) has been prepared by refluxing over P2O5 for 8hours, then fractionally distilling, and storing with activated alumina. m-Dichlorobenzene dissolves rubber stoppers. [Beilstein 5 IV 657.] |
1,3-Dichlorobenzene Preparation Products And Raw materials | |
Preparation Products | Imazalil-->1,4-Dichlorobenzene-->1,3-Dicyanobenzene-->2,4-Difluoroaniline-->Itraconazole-->Tracid Brilliant Red 10b-->2',4'-Dichloroacetophenone-->2,4-Dichlorobenzenesulfonyl chloride-->2,4-Dichlorobenzotrifluoride-->2-Bromo-2',4'-dichloroacetophenone-->2,4-Dichloronitrobenzene-->4-(4-chlorophenoxy-2‘-chlorophenyl-α-bromo ethanone)-->ETACONAZOLE-->2',4'-Dichlorovalerophenone |
Raw materials | Sodium nitrite-->Chlorine-->Calcium chloride-->Cuprous chloride-->Potassium iodide-->Chlorobenzene-->1,2-Dichlorobenzene-->Nitrobenzene-->m-Phenylenediamine-->2-Chloroaniline-->3-Chloroaniline-->1,3-Dinitrobenzene-->p-Dichlorobenzene-->Adsorbent-->DICHLOROBENZENE MIXTURE-->starch-iodide indicator |
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