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  • Product Name:   1,2-Dichlorobenzene
  • Synonyms:   NSC 60644;1.2-DICHLOROBENZENE HPLC/SPECTRO
  • CAS No.:   95-50-1
  • Molecular Formula:   C6H4Cl2
  • Molecular Weight :   147
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of 1,2-Dichlorobenzene



1,2-Dichlorobenzene Chemical Properties


Melting point  -15 °C


Boiling point  179 °C


density  1.306 g/mL at 25 °C(lit.)


vapor density  5.1 (vs air)


vapor pressure  1.2 mm Hg ( 20 °C)


refractive index  n20/D 1.551


Fp  150 °F


storage temp.  0-6°C


solubility  0.13g/l


form  Liquid


color  Clear colorless to very slightly yellow


explosive limit 2.2-12%(V)


Water Solubility  0.13 g/L (20 ºC)


Merck  14,3056


BRN  606078


Stability: Stable, but possibly light sensitive. Combustible. Incompatible with oxidizing agents, aluminium, aluminium alloys. Attacks some rubbers and plastics.


CAS DataBase Reference 95-50-1(CAS DataBase Reference)


NIST Chemistry Reference Benzene, 1,2-dichloro-(95-50-1)


EPA Substance Registry System Benzene, 1,2-dichloro-(95-50-1)




Safety Information


Hazard Codes  Xn,N,Xi,F,T


Risk Statements  22-36/37/38-50/53-67-66-52/53-36-11-39/23/24/25-23/24/25-51/53


Safety Statements  9-16-26-60-61-23-45-36/37-7


RIDADR  UN 1993 3/PG 2


WGK Germany  3


RTECS  CZ4500000


TSCA  Yes


HazardClass  6.1


PackingGroup  III


HS Code  29036100


Hazardous Substances Data 95-50-1(Hazardous Substances Data)




1,2-Dichlorobenzene Usage And Synthesis


Chemical Properties colourless liquid


Definition ChEBI: A dichlorobenzene carrying chloro substituents at positions 1 and 2.


Uses Solvent for waxes, gums, resins, tars, rubbers, oils, asphalts; insecticide for termites and locust borers; fumigant; deodorizer; removing sulfur from illuminating gas; as degreasing agent for metals, leather, wool; as ingredient of metal polishes; as heat transfer medium; as intermediate in the manufacture of dyes.


General Description A clear colorless liquid with a pleasant odor. Denser than water and insoluble in water. Flash point 150°F. Toxic by inhalation and ingestion. Used to make other chemicals, solvents, fumigants and insecticides and for many other uses.


Air & Water Reactions Insoluble in water.


Reactivity Profile 1,2-Dichlorobenzene is sensitive to prolonged exposure to light. 1,2-Dichlorobenzene can react vigorously with oxidizers. 1,2-Dichlorobenzene is incompatible with aluminum and aluminum alloys. 1,2-Dichlorobenzene attacks some forms of plastics, rubber and coatings. .


Health Hazard Chronic inhalation of mist or vapors may result in damage to lungs, liver, and kidneys. Acute vapor exposure can cause symptoms ranging from coughing to central nervous system depression and transient anesthesia. Irritating to skin, eyes, and mucous membranes. May cause dermatitis.


Fire Hazard Special Hazards of Combustion Products: Poisonous vapors including hydrogen chloride gas, chlorocarbons, chlorine


Purification Methods Contaminants may include the p-isomer and trichlorobenzene [Suslick et al. J Am Chem Soc 106 4522 1984]. It should be shaken with conc or fuming H2SO4, washed with water, dried with CaCl2, and distilled from CaH2 or sodium in a glass-packed column. Low conductivity material (ca 10-10 mhos) has been obtained by refluxing with P2O5, fractionally distilling and passing it through a column packed with silica gel or activated alumina: it is stored in a dry-box under N2 or with activated alumina. [Beilstein 5 IV 654.]




1,2-Dichlorobenzene Preparation Products And Raw materials


Raw materials Benzene-->Chlorine-->Cuprous chloride-->2-Chloroaniline


Preparation Products 3,5-Dichloroaniline-->Norfloxacin-->METHYLISOCYANATE 1 X 500MG NEAT-->Coumarin 6-->Pigment Geen 7-->Butyl isocyanate-->3,4-Dichloroaniline-->3-Amino-5-methylisoxazole-->Mebendazole-->VAT BLACK 27-->3-Chloro-4-fluoroaniline-->Permanent Violet RL-->1,4-Dichlorobenzene-->DIRECT YELLOW 27-->2,6-Dichlorobenzonitrile-->3,4-Dichloronitrobenzene-->1,2,4,5-TETRACYANOBENZENE-->Acenaphthenequinone-->1,3-Dichloroisoquinoline-->4-(3-METHYL-UREIDO)-BENZENESULFONYL CHLORIDE-->1,2,4,5-BENZENETETRACARBOXAMIDE-->1-Naphthyl isocyanate-->N,N,N',N'-Tetraphenylbenzidine-->2,7-DIBROMO-9H-CARBAZOLE-->2,4,6-Trimethoxybenzaldehyde-->PYROMELLITIC DIIMIDE-->3,7-dichloro-8-dichloro methyl quinoline-->3,7-dichloro-8-chloro methyl quinoline-->2-NAPHTHYL ISOCYANATE-->4,5-Dichloro-1,2-benzenediamine-->3,4-Dichlorobenzophenone-->3,5-Dibromo-4-hydroxybenzaldehyde-->Pigment Red 176-->(3,4-Diaminophenyl)phenylmethanone-->tert-Butylisocyanate-->Acetofenate-->C. I. Pigment Yellow 173-->3,4-Dichlorobenzaldehyde-->DICHLORPHENAMIDE-->4,5-DICHLORO-BENZENE-1,3-DISULFONYLDICHLORIDE


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