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  • Product Name:   Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
  • Synonyms:   Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate;Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate;Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis;(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate;RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX
  • CAS No.:   35138-22-8
  • Molecular Formula:   C16H24BF4Rh
  • Molecular Weight :   406.07
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate



Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties


Melting point  210 °C


density  0.42 g/cm3 (20℃)


storage temp.  Refrigerator (+4°C)


form  Powder


color  Red


PH 7 (5g/l, H2O, 20℃)


Water Solubility  insoluble


Sensitive  Slightly air & moisture sensitive


CAS DataBase Reference 35138-22-8(CAS DataBase Reference)




Safety Information


Hazard Codes  F,Xi


Risk Statements  11-34


Safety Statements  16-45-36/37/39-26


RIDADR  UN 2921


Hazard Note  Irritant


HazardClass  8


PackingGroup  III




Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Usage And Synthesis


Uses
  1. Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
  2. Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions. 


Chemical Properties dark red




Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials


Raw materials Etanol-->Ethyl acetate-->1,5-Cyclooctadiene-->Silver tetrafluoroborate -->Rhodium (III) chloride trihydrate


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