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  • Product Name:   Bis(triphenylphosphine)palladium(II) chloride
  • Synonyms:   DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADATE (II);DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM;DICHLOROBIS(TRIPHENYLPHOSPHINE)PALLADIUM(II);BIS(TRIPHENYLPHOSPHINE)PALLADIUM CHLORIDE;BIS-(TRIPHENYLPHOSPHINE)-PALLADIUM DICHLORIDE
  • CAS No.:   13965-03-2
  • Molecular Formula:   C36H30Cl2P2Pd
  • Molecular Weight :   701.9
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Bis(triphenylphosphine)palladium(II) chloride



Bis(triphenylphosphine)palladium(II) chloride Chemical Properties


Melting point  260°C


RTECS  RT3578000


storage temp.  Store below +30°C.


form  Powder


color  Yellow


Water Solubility  Insoluble in water. Soluble in benzene, and toluene.


Sensitive  Hygroscopic


CAS DataBase Reference 13965-03-2(CAS DataBase Reference)




Safety Information


Hazard Codes  Xn


Risk Statements  36/37/38-22-40-19


Safety Statements  37/39-26-36/37


WGK Germany  3


3-10-21


HS Code  28439090




Bis(triphenylphosphine)palladium(II) chloride Usage And Synthesis


Reactions
  1. Precatalyst for the carbonylative cyclization of malonate derivatives.
  2. Catalyst used in the double allylation of activated olefins.
  3. Precatalyst for the three-component preparation of 3-arylidene- (or 3-alkenylidene) tetrahydrofurans.
  4. Precatalyst for the homocoupling of terminal alkynes.
  5. Precatalyst in the cross-coupling of alkynylsilanols and aryl halides.
  6. Catalyst for direct Pd-catalyzed alkynylation of N-fused heterocycles.
  7. Catalyst for a tandem Heck reaction/C-H functionalization.
  8. Catalyst for direct arylation of tautomerizable heterocycles. 




Chemical Properties yellow solid


Uses suzuki reaction


Uses Dichlorobis(triphenylphosphine) Palladium (II) is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of me tallacyclic complexes which show antiinflammatory and antifungal properties.




Bis(triphenylphosphine)palladium(II) chloride Preparation Products And Raw materials


Raw materials Etanol-->Ethyl acetate-->Toluene-->Acetonitrile-->Hydrazine hydrate-->Triphenylphosphine-->Palladium chloride


Preparation Products 4-PHENYLETHYNYLPHTHALIC ANHYDRIDE-->2-CHLORO-7H-PYRROLO[2,3-D]PYRIMIDINE-->5-(2-PHENYLETH-1-YNYL)THIOPHENE-2-CARBALDEHYDE-->4-Azaindole-->4-ETHYNYLANILINE


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