4-(Methylthio)phenylboronic acid Chemical Properties | |
Melting point | 210-214 °C(lit.) |
storage temp. | 0-6°C |
form | Crystalline Powder |
color | Off-white |
BRN | 3247219 |
CAS DataBase Reference | 98546-51-1(CAS DataBase Reference) |
Safety Information | |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 37/39-26-36-7/9 |
WGK Germany | 3 |
Hazard Note | Irritant |
HazardClass | IRRITANT |
4-(Methylthio)phenylboronic acid Usage And Synthesis | |
Chemical Properties | Off-white crystalline powder |
Uses | Reactant involved in:• ;Suzuki-Miyaura cross coupling reactions1 with 2-aryl-1-bromo-1-nitroethenes2 or alkynyl bromides3• ;Addition reactions with naphthyridine N-oxides4• ;Oxyarylation of Heck reaction intermediates for synthesis of THF derivatives5• ;Sulfoxidation reactions6• ;Copper-catalyzed halogenation7 |
Uses | suzuki reaction |
4-(Methylthio)phenylboronic acid Preparation Products And Raw materials | |
Preparation Products | 6-(4-METHYLSULFANYLPHENYL)PYRIDINE-2-CARBALDEHYDE |
Raw materials | n-Butyllithium-->Dimethyl sulfate-->Trimethyl borate-->4-BROMOTHIOPHENOL |
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