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  • Product Name:   Ruthenium(III) chloride
  • Synonyms:   Trichlororuthenium hydrate;RUTHENIUM(+3)CHLORIDE HYDRATE
  • CAS No.:   14898-67-0
  • Molecular Formula:   Cl3Ru
  • Molecular Weight :   207.43
  • Specification :   98%
  • Place of Origin:   China
  • Appearance :   
  • Document :   Download

Description of Ruthenium(III) chloride
Ruthenium(III) chloride Chemical Properties
Melting point  >300°C
density  3.11 g/cm3
storage temp.  Store at +5°C to +30°C.
form  Powder
color  Dark brown to black
PH <2 (H2O, 20℃)Aqueous solution
Water Solubility  soluble
Sensitive  Hygroscopic
Merck  14,8302
Stability: hygroscopic
CAS DataBase Reference 14898-67-0(CAS DataBase Reference)
Safety Information
Hazard Codes  C
Risk Statements  34-52/53-22
Safety Statements  26-36/37/39-45-61
RIDADR  UN 3260 8/PG 2
WGK Germany  2
RTECS  VM2650000
TSCA  Yes
HazardClass  8
PackingGroup  III
Ruthenium(III) chloride Usage And Synthesis
Chemical Properties dark brown to black powder
Uses Catalyzes the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.1
Purification Methods Dissolve the salt in H2O, filter and concentrate to crystallisation in the absence of air to avoid oxidation. Evaporate the solution in a stream of HCl gas while being heated just below its boiling point until a syrup is formed and finally to dryness at 80-100o and dried in a vacuum over H2SO4. When heated at 700o in the presence of Cl2 the insoluble -form is obtained [Grube in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1598 1965, Carlsen et al. J Org Chem 46 3936 1981].
Ruthenium(III) chloride Preparation Products And Raw materials
Preparation Products 3-BROMO-6-METHYL-2-OXO-1(2H)-PYRAZINEACETIC ACID ETHYL ESTER-->ethyl 2-(3,4-dihydro-6-methyl-2,3-dioxopyrazin-1(2H)-yl)acetate-->Tris(triphenylphosphine)ruthenium(II) chloride-->Dichloro(cycloocta-1,5-diene)ruthenium(II)-->TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE

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