| 3-Nitrotoluene Chemical Properties | |
| Melting point | 15 °C |
| Boiling point | 230-231 °C(lit.) |
| density | 1.157 g/mL at 25 °C(lit.) |
| vapor density | 4.73 (vs air) |
| vapor pressure | 1 mm Hg ( 50.2 °C) |
| refractive index | n |
| Fp | 215 °F |
| storage temp. | 2-8°C |
| solubility | 0.419g/l |
| form | Liquid |
| color | Clear yellow to yellow-brownish |
| explosive limit | 2.2%(V) |
| Water Solubility | insoluble |
| Merck | 14,6650 |
| BRN | 1906910 |
| Stability: | Stable. Combustible. Incompatible with reducing agents, strong oxidizing agents, strong bases. |
| CAS DataBase Reference | 99-08-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzene, 1-methyl-3-nitro-(99-08-1) |
| EPA Substance Registry System | Benzene, 1-methyl-3-nitro-(99-08-1) |
| Safety Information | |
| Hazard Codes | T,F,Xn |
| Risk Statements | 23/24/25-33-51/53-36/37/38-11-36-20/21/22 |
| Safety Statements | 36/37-45-61-37-28A-27-16-26 |
| RIDADR | UN 1664 6.1/PG 2 |
| WGK Germany | 2 |
| RTECS | XT2975000 |
| TSCA | Yes |
| HazardClass | 6.1 |
| PackingGroup | II |
| HS Code | 29042000 |
| Hazardous Substances Data | 99-08-1(Hazardous Substances Data) |
| 3-Nitrotoluene Usage And Synthesis | |
| Chemical Properties | yellow-green liquid |
| Definition | ChEBI: A mononitrotoluene carrying a nitro group at position 3. |
| General Description | Yellow crystals that melt at 59°F to a yellow liquid. Often therefore encountered as a liquid. Flash point 223°F. Boiling point 450°F. Insoluble in water. Toxic by inhalation and ingestion. |
| Air & Water Reactions | Insoluble in water. |
| Reactivity Profile | 3-Nitrotoluene reacts with sulfuric acid, strong oxidizing agents and reducing agents. |
| Health Hazard | INHALATION, INGESTION OR SKIN ABSORPTION: Headache, flushing of face, dizziness, difficult breathing, cyanosis, nausea, vomiting, muscular weakness, increased pulse and respiratory rate, irritability and convulsions. EYES: Slight irrita- tion. SKIN: Slight irritation. |
| Purification Methods | Dry 3-nitrotoluene over P2O5 for 24hours, then fractionally distil it under reduced pressure. [Clark & Taylor Org. Synth Coll Vol I 415 1941, Beilstein 5 IV 847.] |
| 3-Nitrotoluene Preparation Products And Raw materials | |
| Preparation Products | 4-Nitrotoluene-->3-Nitrobenzaldehyde-->m-Toluidine-->3-AMINO-N,N-DIMETHYLBENZYLAMINE-->TERT-BUTYL 2-(N-(3-AMINOBENZYL)-N-METHYLAMINO)ACETATE-->3-Aminobenzylmethylamine-->2,4-Dinitrotoluene-->3-Nitrobenzoic acid-->3-Hydroxy-N-(3-nitrophenyl)-2-naphthalenecarboxamide-->3-Nitrobenzyl bromide-->4-Chloro-3-nitrotoluene-->3-Fluorotoluene-->2,3-DINITROTOLUENE-->3,4-DINITROTOLUENE |
| Raw materials | Toluene-->Nitric acid-->4-Nitrotoluene-->2-Nitrotoluene-->p-Toluidine |
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